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Research on Soluble Metal Sulfides: From Polysulfido Complexes to Functional Models for the Hydrogenases.

Authors :
Rauchfuss, Thomas B.
Source :
Inorganic Chemistry. 1/12/2004, Vol. 43 Issue 1, p14-26. 13p. 1 Color Photograph, 20 Diagrams.
Publication Year :
2004

Abstract

Cites four themes of the research on soluble metal sulfides. Synthesis from polysulfido complexes to functional models for the hydrogenases; Use of exothermic disulfurization of polysulfido complexes to generate clusters and rings; Role of donor solvents on the reaction of metals with sulfur; Exploration of the organic and organometallic chemistry of the tetrathiometalates; Structural model for bio-organometallic centers.

Details

Language :
English
ISSN :
00201669
Volume :
43
Issue :
1
Database :
Academic Search Index
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
12212584
Full Text :
https://doi.org/10.1021/ic0343760