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Coupling effect on charge-transfer mechanism of surface-enhanced resonance Raman scattering.
- Source :
-
Journal of Raman Spectroscopy . Apr2017, Vol. 48 Issue 4, p560-569. 10p. - Publication Year :
- 2017
-
Abstract
- In this work, charge-transfer mechanism of surface-enhanced resonance Raman scattering (SERRS) spectroscopy of pyrazine absorbed on Ac@Au7 clusters is theoretically investigated, and the coupling effect between the nanoparticles is especially concerned. First, the contributions of coupling effect to surface-enhanced Raman scattering (SERS) are compared between the ground-state nanoparticles. Second, the visualization of charge transfer provides evidence for the coupling effect on the charge-transfer enhancement mechanism of SERRS spectroscopy. The theoretical results show that the coupling effect on charge-transfer mechanism of SERRS can significantly enhance the intensity of SERS spectra up to about 6 × 105 times. The different coupling ways not only result in different degree of charge transfer on electronic transitions, but also cause different intensity of charge-transfer absorption peaks. Both of them strongly influence the enhancement of charge-transfer mechanism of SERRS. This study promotes the understanding of charge-transfer enhancement mechanism of SERRS for ultrasensitive Raman spectral analysis at nanoscale. Copyright © 2017 John Wiley & Sons, Ltd. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03770486
- Volume :
- 48
- Issue :
- 4
- Database :
- Academic Search Index
- Journal :
- Journal of Raman Spectroscopy
- Publication Type :
- Academic Journal
- Accession number :
- 122406203
- Full Text :
- https://doi.org/10.1002/jrs.5077