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Recovery of zirconium from pickling solution, regeneration and its reuse.
- Source :
-
Nuclear Engineering & Design . May2017, Vol. 316, p89-92. 4p. - Publication Year :
- 2017
-
Abstract
- The pressurized heavy water reactors use natural uranium oxide (UO 2 ) as fuel and uses cladding material made up of zircaloy, an alloy of zirconium. Pickling of zircaloy tubes and appendages viz. , spacer and bearing pads is carried out to remove the oxide layer and surface contaminants, if present. Pickling solution, after use for many cycles i.e. , used pickling solution (UPS) is sold out to vendors, basically for its zirconium value. UPS, containing a relatively small concentration of hydrofluoric acid. After repeated use, pickling solution become saturated with zirconium fluoride complex and is treated by adding sodium nitrate to precipitate sodium hexafluro-zirconate. The remaining solution can be recycled after suitable makeup for further pickling use. The revenue lost by selling UPS is very high compared to its zirconium value, which causes monetary loss to the processing unit. Experiments were conducted to regenerate and reuse UPS which will save a good amount of revenue and also protect the environment. Experimental details and results are discussed in this paper. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00295493
- Volume :
- 316
- Database :
- Academic Search Index
- Journal :
- Nuclear Engineering & Design
- Publication Type :
- Academic Journal
- Accession number :
- 122478541
- Full Text :
- https://doi.org/10.1016/j.nucengdes.2017.03.006