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Addition of N-nucleophiles to gold(iii)-bound isocyanides leading to short-lived gold(iii) acyclic diaminocarbene complexes.
- Source :
-
New Journal of Chemistry . 5/7/2017, Vol. 41 Issue 9, p3246-3250. 5p. - Publication Year :
- 2017
-
Abstract
- Reaction of [AuCl3(CNR1)] (R1 = Xyl, Cy, (S)-CHMePh) with amines unexpectedly proceeds via the redox pathway giving gold(i)–isocyanides and imines, while the addition of benzophenone hydrazone to the isocyanide ligand in [AuCl3(CNR1)] at RT leads to short-lived gold(iii) acyclic diaminocarbene complexes [AuCl3{C(NHNCPh2)NHR1}]. [ABSTRACT FROM AUTHOR]
- Subjects :
- *METAL complexes
*GOLD compounds
*NUCLEOPHILES
Subjects
Details
- Language :
- English
- ISSN :
- 11440546
- Volume :
- 41
- Issue :
- 9
- Database :
- Academic Search Index
- Journal :
- New Journal of Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 122851425
- Full Text :
- https://doi.org/10.1039/c7nj00529f