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Ferroelectric phase transitions of the 0.32PIN-0.345PMN-0.335PT single crystals studied by temperature-dependent Raman spectroscopy, dielectric and ferroelectric performance.
- Source :
-
Phase Transitions . May2017, Vol. 90 Issue 5, p500-508. 9p. - Publication Year :
- 2017
-
Abstract
- The ferroelectric phase transition characteristics of the 0.32Pb(In1/2Nb1/2)O3-0.345Pb(Mg1/3Nb2/3)O3-0.335PbTiO3(0.32PIN-0.345PMN-0.335PT) single crystals were studied by the temperature-dependent Raman spectroscopy and some electrical properties. Ferroelectric monoclinic phase was confirmed at room temperature by the numbers of the Raman modes. Successive ferroelectric phase transitions, i.e. ferroelectric monoclinic phase to ferroelectric tetragonal phase transition (FEM-FET) and ferroelectric tetragonal phase to paraelectric cubic phase transition (FET-PC), are evidenced by the anomalies of Raman modes line width, peaks intensity and their ratios aroundTM-TandTC/Tmtemperatures. The temperature dependent permittivity derivative ξ =dϵ/dTnot only provides further evidence of the successive ferroelectric phase transitions, but also demonstrates the second-order transition characteristic of the FEM-FETphase transition and the first-order transition feature of the FET-PCphase transition. The FEM-FETphase transition is also confirmed by the abnormal narrowing of the P-E loops, decrease of thePrandEcvalues, and extremums of the pyroelectric performance. [ABSTRACT FROM PUBLISHER]
Details
- Language :
- English
- ISSN :
- 01411594
- Volume :
- 90
- Issue :
- 5
- Database :
- Academic Search Index
- Journal :
- Phase Transitions
- Publication Type :
- Academic Journal
- Accession number :
- 122903183
- Full Text :
- https://doi.org/10.1080/01411594.2016.1227987