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Protein Trapping in Plasmonic Nanoslit and Nanoledge Cavities: The Behavior and Sensing.

Authors :
Noyhouzer, Tomer
Snowden, Michael E.
Tefashe, Ushula M.
Mauzeroll, Janine
Source :
Analytical Chemistry. 5/16/2017, Vol. 89 Issue 10, p5221-5253. 9p.
Publication Year :
2017

Abstract

A new type of flow platform for electrochemical and spectroelectrochemical measurements is presented. Finite element method simulations confirm that the hydrodynamic profile within the device is not turbulent and provides an analytical platform for the investigation of homogeneous kinetics, radical lifetimes, and reaction mechanisms. The modular "plug and play" configuration of the platform allows one to carry out electrochemistry and spectroscopy individually or simultaneously. Specific demonstrations of electroanalytical measurements using the flow system platform includes voltammetric analysis of organometallic compounds and quantitative analysis of ascorbic acid in commercial orange juice samples. Combined spectroelectrochemical demonstrations include electrochemical luminescence of ruthenium compounds and ligand exchange reactions of iron complexes using UV-vis spectroscopy. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00032700
Volume :
89
Issue :
10
Database :
Academic Search Index
Journal :
Analytical Chemistry
Publication Type :
Academic Journal
Accession number :
123181990
Full Text :
https://doi.org/10.1021/acs.analchem.6b04493