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Ultrahigh-resolution spectroscopy for methyl mercaptan at the ν2-band by a distributed feedback interband cascade laser.
- Source :
-
Journal of Quantitative Spectroscopy & Radiative Transfer . Jul2017, Vol. 196, p123-129. 7p. - Publication Year :
- 2017
-
Abstract
- The ultrahigh-resolution mid-infrared absorption spectrum of methyl mercaptan (CH 3 SH) was recorded and analyzed in the region of 2945–2953 cm -1 , where the strong ν 2 -band is located. Benefitting from the high-resolution of tunable laser absorption spectrometry (TLAS) with a distributed feedback interband cascade laser (DFB-ICL), 12-strong and 27-weak air-broadened absorption peaks belonging to the ν 2 -band of CH 3 SH were assigned with resolution of better than 2.24×10 -5 cm -1 (~26 fm/670 kHz) and absorption cross section precision of 2.0%, at temperature of 298.15 K and pressure of 1 atm. For further description of the assigned transitions, the spectral line parameters and cross sections of these absorption peaks versus pressure were investigated. These ultrahigh resolution air-broadened spectra can be used as reference data for CH 3 SH remote sensing and absolute spectral measurement applications. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00224073
- Volume :
- 196
- Database :
- Academic Search Index
- Journal :
- Journal of Quantitative Spectroscopy & Radiative Transfer
- Publication Type :
- Academic Journal
- Accession number :
- 123374355
- Full Text :
- https://doi.org/10.1016/j.jqsrt.2017.03.027