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A novel high yield polyborosilazane precursor for SiBNC ceramic fibers.
- Source :
-
Ceramics International . Sep2017, Vol. 43 Issue 13, p10576-10580. 5p. - Publication Year :
- 2017
-
Abstract
- A novel processable and high yield polyborosilazane (PBSZ) precursor for SiBNC ceramic fibers was synthesized via boron trichloride (BCl 3 ), co-polymerization of trichlorosilane (SiHCl 3 ) and methylamine (MeNH 2 ), followed by trans-amination with NH 3 . The synthesized PBSZ precursor was characterized and the results showed that the polymeric precursor exhibited good melt–processability and green fibers with a diameter of 45 µm could be easily obtained by melt spinning. The green fibers were subsequently pyrolyzed at 1200 °C in nitrogen atmospheres to provide SiBNC ceramic fibers with a cylindrical hollow structure, ca.32 µm in diameter and 720 MPa in tensile strength. The green fibers had an approximately ceramic yield of 78% at 900 °C. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 02728842
- Volume :
- 43
- Issue :
- 13
- Database :
- Academic Search Index
- Journal :
- Ceramics International
- Publication Type :
- Academic Journal
- Accession number :
- 123374768
- Full Text :
- https://doi.org/10.1016/j.ceramint.2017.04.120