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Exploring Pd/AlO Catalysed Redox Isomerisation of Allyl Alcohol as a Platform to Create Structural Diversity.
- Source :
-
Catalysis Letters . Jul2017, Vol. 147 Issue 7, p1834-1843. 10p. - Publication Year :
- 2017
-
Abstract
- We report our results on exploiting the different reactivities present in the catalytic cycle of the Pd/AlO catalyzed redox isomerization of allyl alcohol. We show that the reactivity of allyl alcohol derived acrolein and enol can be involved in further cascade reactions leading to a diverse set of products. While the oxidation product acrolein can react via Michael and oxa-Michael reactions, the isomerization product enol can be readily involved in aldol condensation processes. Salicylaldehydes, that are able to react on their electrophilic carbonyl and nucleophilic OH-groups with allyl alcohol derived enol and acrolein, respectively, are used to explore conditions where the structure of the product heterocycles can be controlled. Graphical Abstract: [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 1011372X
- Volume :
- 147
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- Catalysis Letters
- Publication Type :
- Academic Journal
- Accession number :
- 123456829
- Full Text :
- https://doi.org/10.1007/s10562-017-2087-4