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Syntheses and post-functionalization of tri-substituted polyalkoxohexavanadates containing tris(alkoxo) ligands.
- Source :
-
Dalton Transactions: An International Journal of Inorganic Chemistry . 7/14/2017, Vol. 46 Issue 26, p8505-8513. 9p. - Publication Year :
- 2017
-
Abstract
- A new synthetic approach to tri-substituted trisalkoxy-hexavanadate clusters containing different organic groups was developed in this work. Four mixed-valence or fully reduced POV hybrids were synthesized and structurally characterized, including an amino-containing derivative of hexavanadate, Na2[VIV3VV3O10{NH2C(CH2O)3}3] (1). Furthermore, a novel mixed-valence POV hybrid was prepared via the amidation of 1, indicating that 1 can be used as an excellent building block for the design and synthesis of mixed-valence POV functional materials. [ABSTRACT FROM AUTHOR]
- Subjects :
- *VANADATES
*METAL clusters
*VALENCE (Chemistry)
Subjects
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 46
- Issue :
- 26
- Database :
- Academic Search Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 123915540
- Full Text :
- https://doi.org/10.1039/c7dt01543g