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Spin States of Homochiral and Heterochiral Isomers of [Fe(PyBox)2]2+ Derivatives.
- Source :
-
Chemistry - A European Journal . 7/6/2017, Vol. 23 Issue 38, p9067-9075. 9p. - Publication Year :
- 2017
-
Abstract
- The following iron(II) complexes of 2,6- bis(oxazolinyl)pyridine (PyBox; LH) derivatives are reported: [Fe( LH)2][ClO4]2 ( 1); [Fe(( R)- LMe)2][ClO4]2 (( R)- 2; LMe=2,6- bis{4-methyloxazolinyl}pyridine); [Fe(( R)- LPh)2][ClO4]2 (( R)- 3) and [Fe(( R)- LPh)(( S)- LPh)][ClO4]2 (( RS)- 3; LPh=2,6- bis{4-phenyloxazolinyl}pyridine); and [Fe(( R)- L iPr)2][ClO4]2 (( R)- 4) and [Fe(( R)- L iPr)(( S)- L iPr)][ClO4]2 (( RS)- 4; L iPr=2,6- bis{4- isopropyloxazolinyl}pyridine). Solid ( R)- 3â‹…MeNO2 exhibits an unusual very gradual, but discontinuous thermal spin-crossover with an approximate T [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09476539
- Volume :
- 23
- Issue :
- 38
- Database :
- Academic Search Index
- Journal :
- Chemistry - A European Journal
- Publication Type :
- Academic Journal
- Accession number :
- 123951334
- Full Text :
- https://doi.org/10.1002/chem.201700820