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Facile synthesis of NHC-stabilized Ni nanoparticles and their catalytic application in the Z-selective hydrogenation of alkynes.
- Source :
-
Chemical Communications . 7/18/2017, Vol. 53 Issue 56, p7894-7897. 4p. - Publication Year :
- 2017
-
Abstract
- Well defined Ni nanoparticles (NiNPs) stabilized with N-heterocyclic carbenes (NHCs) have been synthesized through a new methodology involving the decarboxylation of a zwitterionic CO2 adduct. Their catalytic performance was tested in the partial hydrogenation of alkynes into (Z)-alkenes under very mild reaction conditions (50 °C and 5 bar H2 pressure), providing excellent activities and selectivities. [ABSTRACT FROM AUTHOR]
- Subjects :
- *NANOPARTICLE synthesis
*NICKEL compounds
*CATALYTIC activity
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 53
- Issue :
- 56
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 124057198
- Full Text :
- https://doi.org/10.1039/c7cc01779k