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Rhodium(III)-Catalyzed Selective C- Acetoxylation and Hydroxylation Reactions.
- Source :
-
Organic Letters . Jul2017, Vol. 19 Issue 13, p3532-3535. 4p. - Publication Year :
- 2017
-
Abstract
- An efficient Cp*Rh(III)-catalyzed, chelation-assisted C(sp²)-H acetoxylation and hydroxylation reaction has been developed for the first time. The reaction proceeds under mild conditions and allows for selective preparation of C-H acetoxylation and hydroxylation products, thus providing a good complement to previous C-H oxygenation reactions and expanding the field of Cp*Rh(III)-catalyzed C-H functionalizations. [ABSTRACT FROM AUTHOR]
- Subjects :
- *RHENIUM catalysts
*OXYGENATION (Chemistry)
Subjects
Details
- Language :
- English
- ISSN :
- 15237060
- Volume :
- 19
- Issue :
- 13
- Database :
- Academic Search Index
- Journal :
- Organic Letters
- Publication Type :
- Academic Journal
- Accession number :
- 124115731
- Full Text :
- https://doi.org/10.1021/acs.orglett.7b01494