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Synthesis of light-driven motorized nanocars for linear trajectories and their detailed NMR structural determination.
- Source :
-
Tetrahedron . Aug2017, Vol. 73 Issue 33, p4864-4873. 10p. - Publication Year :
- 2017
-
Abstract
- The design and synthesis of a fluorescent light-driven motorized nanocar with a linear geometry is described. Due to its structural design, the nanocar is present as a mixture of two photo-interconvertible diastereomers. An extensive and detailed NMR study allowed the full assignment of the chemical shifts of the two diastereomers in the mixture. The nanocar is expected to translate in a linear motion due to the light-driven motor providing a paddle-wheel like propulsion. The quantum yield of 0.56 and the photostability of the dye make this nanocar suitable for future single-molecule fluorescence microscopy studies. [ABSTRACT FROM AUTHOR]
- Subjects :
- *NANOCAR
*NANOPARTICLES
*DIASTEREOISOMERS
*OPTICAL isomers
*SINGLE molecules
Subjects
Details
- Language :
- English
- ISSN :
- 00404020
- Volume :
- 73
- Issue :
- 33
- Database :
- Academic Search Index
- Journal :
- Tetrahedron
- Publication Type :
- Academic Journal
- Accession number :
- 124301453
- Full Text :
- https://doi.org/10.1016/j.tet.2017.05.063