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The preparation and cycloaddition reaction of 1-sulfonyl-1-trifluoromethyl allenes.
- Source :
-
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry . Aug2017, Vol. 58 Issue 34, p3377-3379. 3p. - Publication Year :
- 2017
-
Abstract
- A series of 1-sulfonyl-1-trifluoromethyl allenes were prepared for the first time from commercial available 2-bromo-3,3,3-trifluoropropene. Cycloaddition reaction of these trifluoromethylated allenes with nitrones occured readily under mild conditions, giving the corresponding trifluoromethylated isoxazolidines in high yields. [ABSTRACT FROM AUTHOR]
- Subjects :
- *CHEMICAL reactions
*RING formation (Chemistry)
*ALLENE
*SULFONYL compounds
*PROPENE
Subjects
Details
- Language :
- English
- ISSN :
- 00404039
- Volume :
- 58
- Issue :
- 34
- Database :
- Academic Search Index
- Journal :
- Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 124403489
- Full Text :
- https://doi.org/10.1016/j.tetlet.2017.07.050