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Manganese-catalyzed synthesis of monofluoroalkenes via C–H activation and C–F cleavage.
- Source :
-
Chemical Communications . 8/11/2017, Vol. 53 Issue 62, p8731-8734. 4p. - Publication Year :
- 2017
-
Abstract
- The manganese-catalyzed α-fluoroalkenylation of arenes via C–H activation and C–F cleavage has been described. This protocol provides a very useful method for the synthesis of monofluoroalkenes with predominant unconventional E-isomer selectivity which complements the existing strategies for the access to these molecular architectures. In addition, the selectivity of β-defluorination in the catalytic cycle not only determines the configurations of the products but also obviates the use of external oxidants, providing a good example in the exploitation of manganese-catalyzed redox-neutral C–H transformations. [ABSTRACT FROM AUTHOR]
- Subjects :
- *MANGANESE catalysts
*CARBON-hydrogen bonds
*ORGANIC chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 53
- Issue :
- 62
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 124419390
- Full Text :
- https://doi.org/10.1039/c7cc04131d