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A new strategy to remarkably improve the low-temperature reversible hydrogen desorption performances of LiBH4 by compositing with fluorographene.
- Source :
-
International Journal of Hydrogen Energy . Aug2017, Vol. 42 Issue 31, p20046-20055. 10p. - Publication Year :
- 2017
-
Abstract
- LiBH 4 is a promising hydrogen storage material for its large capacity. However, high desorption temperature, sluggish kinetics and demanding rehydrogenation severely hinder its practical use. Surface functional groups of graphene in many cases are treated as effective approaches to obtain some kinds of excellent properties of energy storage materials. In the current work, a new facile and effective strategy to improve the reversible hydrogen desorption properties of LiBH 4 is proposed by composing with functionalized graphene to form the LiBH 4 –fluorographene composite. The fluorographene (FG) nanosheets are successfully exfoliated from fluorographite (FGi) and composed with LiBH 4 . It is demonstrated that the FG can remarkably improve the hydrogen desorption thermodynamics, kinetics and reversibility of LiBH 4 via reactant destabilization method. An extremely fast hydrogen desorption process with a high capacity of 8.2 wt.% at 148.1 °C is achieved in the LiBH 4 –50FG composite. Further research reveals that the enhancement actually roots in the strengthened interfacial interaction between LiBH 4 and exfoliated FG. Moreover, it is confirmed that the LiBH 4 –40FG composite exhibits a significantly enhanced reversible hydrogen desorption capacity of 7.2 wt.% and LiBH 4 is regenerated. Such enhanced reversible hydrogen desorption properties are ascribed to the strengthened interfacial interactions between LiBH 4 and FG with large surface, as well as the formation of LiH x F 1− x phase. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03603199
- Volume :
- 42
- Issue :
- 31
- Database :
- Academic Search Index
- Journal :
- International Journal of Hydrogen Energy
- Publication Type :
- Academic Journal
- Accession number :
- 124421592
- Full Text :
- https://doi.org/10.1016/j.ijhydene.2017.05.060