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A bis-corannulene based molecular tweezer with highly sensitive and selective complexation of C70 over C60.

Authors :
Yang, Deng-Chen
Li, Meng
Chen, Chuan-Feng
Source :
Chemical Communications. 8/28/2017, Vol. 53 Issue 67, p9336-9339. 4p.
Publication Year :
2017

Abstract

A new molecular tweezer with two corannulene subunits linked by a tetrahydro[5]helicene imide was conveniently synthesized, which showed highly sensitive and selective complexation of C70 over C60via concave–convex π–π interactions, and the KC70/KC60 value even was found to be 230/1. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
53
Issue :
67
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
124665818
Full Text :
https://doi.org/10.1039/c7cc03519e