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Mechanochemical Synthesis of Phosphazane-Based Frameworks.
- Source :
-
Chemistry - A European Journal . 8/22/2017, Vol. 23 Issue 47, p11279-11285. 7p. - Publication Year :
- 2017
-
Abstract
- Mechanochemistry is emerging as a powerful solvent-free approach to chemical synthesis, having been applied to metal oxides, pharmaceutical materials, organic compounds and to a lesser extent, coordination complex synthesis. Notably, examples of applications of mechanochemical methodologies in the synthesis of main-group compounds are few and far between. Herein, we demonstrate that ball milling enabled the solvent-free synthesis of a range of phosphazane frameworks with a broad substrate scope, yielding seven new acyclic and macrocyclic species. The strength of this methodology is highlighted by a fast, selective and high-conversion product generation from poorly soluble starting materials, thereby demonstrating mechanochemistry as a real alternative to solution-based methods in synthetic main-group chemistry. [ABSTRACT FROM AUTHOR]
- Subjects :
- *MECHANICAL chemistry
*ORGANIC synthesis
*SOLVENTS
*METALLIC oxides
*PHOSPHAZANES
Subjects
Details
- Language :
- English
- ISSN :
- 09476539
- Volume :
- 23
- Issue :
- 47
- Database :
- Academic Search Index
- Journal :
- Chemistry - A European Journal
- Publication Type :
- Academic Journal
- Accession number :
- 124767062
- Full Text :
- https://doi.org/10.1002/chem.201701619