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Ultrathin α-MnO2 Nanosheets Wrapped on Acanthosphere-like Microspheres with Highly Reversible Performance for Energy Storage.
- Source :
-
Electrochimica Acta . Sep2017, Vol. 247, p745-753. 9p. - Publication Year :
- 2017
-
Abstract
- Architecturally assembling primary building blocks into the expected geometric heterostructure is a tremendous challenge due to the interfaces dislocation and stretch resulting from the lattice-mismatch between heterogeneous building blocks. Although different dimensional nanomaterials have been synthesized, the branched acanthosphere-like hierarchical architecture is needed to be developed and the growth mechanism should be investigated. Here we design and fabricate an acanthosphere-like NiCo 2 O 4 @α-MnO 2 heterostructures architecture by an “in situ growth” technique of two-steps hydrothermal method. The as-prepared acanthosphere-like NiCo 2 O 4 @α-MnO 2 microspheres (denoted as AM-NCM) have a diameter of 5 ∼ 7 um with a highly open and interstitial three dimensional (3D) architecture formed by α-MnO 2 ultrathin nanosheets leading to faster ion diffusion and improved charge transfer kinetics. Therefore, the hybrid electrodes exhibits exceptional specific capacitances of 695 F g −1 (2.17 F cm −2 ) at the current densities of 3.2 A g −1 (10 mA cm −2 ) and good cycling electrochemical stability with only 2.4% capacitance loss after 1000 cycles and still maintains 92% of its initial value after 6000 cycles. The outstanding performance of the branched AM-NCM reveals its potential to be a promising material for energy storage, and also inspires continued research on the formation of branched hierarchical architecture as energy storage materials. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00134686
- Volume :
- 247
- Database :
- Academic Search Index
- Journal :
- Electrochimica Acta
- Publication Type :
- Academic Journal
- Accession number :
- 124838854
- Full Text :
- https://doi.org/10.1016/j.electacta.2017.07.055