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Lone pair-π interaction-induced generation of photochromic coordination networks with photoswitchable conductance.
- Source :
-
Chemical Communications . 9/11/2017, Vol. 53 Issue 70, p9701-9704. 4p. - Publication Year :
- 2017
-
Abstract
- Lone pair-π interaction-induced charge-transfer was successfully used for switching the conductance of a coordination network, through variation of the degree of charge transfer caused by external photostimulation. The underlying mechanism is attributed to the changes in efficient charge-carriers by photoinduced strong charge transfer, which was investigated by in situ UV-Vis absorption, ESR, and computational studies. [ABSTRACT FROM AUTHOR]
- Subjects :
- *NONBONDING electron pairs
*COORDINATE covalent bond
*ELECTRIC admittance
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 53
- Issue :
- 70
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 124880757
- Full Text :
- https://doi.org/10.1039/c7cc05150f