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Enantioselective Synthesis of Spiro[indolizidine-1,3'-oxindoles].

Authors :
Pérez, Maria
Ramos, Carlos
Massi, Lucia
Gazzola, Silvia
Taglienti, Chiara
Yayik, Nihan
Molins, Elies
Viayna, Antonio
Luque, F. Javier
Bosch, Joan
Amat, Mercedes
Source :
Organic Letters. Aug2017, Vol. 19 Issue 15, p4050-4053. 4p.
Publication Year :
2017

Abstract

A three-step procedure for the enantioselective synthesis of spiro[indolizidine-1,3'-oxindoles], consisting of a stereoselective cyclocondensation reaction between (S)-tryptophanol and a prochiral or racemic δ-oxoester, bromination of the resulting oxazolopiperidone lactam, and a final stereoselective spirocyclization, is reported. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
15237060
Volume :
19
Issue :
15
Database :
Academic Search Index
Journal :
Organic Letters
Publication Type :
Academic Journal
Accession number :
124904584
Full Text :
https://doi.org/10.1021/acs.orglett.7b01818