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A structural and functional model of copper(II)-flavonolate ES complex of flavonol 2,4-dioxygenase.
- Source :
-
Inorganica Chimica Acta . Oct2017, Vol. 467, p7-10. 4p. - Publication Year :
- 2017
-
Abstract
- A novel mononuclear copper(II)-flavonolate complex [Cu II L(fla)] (LH: 2-{[bis(pyridine-2-ylmethyl)-amino]methyl}-4-methoxy benzoic acid, flaH: flavonol) was prepared as a structural and functional model of the ES (enzyme-substrate) complex of Cu II -containing flavonol 2,4-dioxygenase. Its structure, properties and reactivity towards molecular dioxygen have been investigated in details. The complex shows the best reactivity in the copper(II)-flavonolate ES model system, may it could be contributed to the approximately monodentate coordination of the substrate flavonolate. [ABSTRACT FROM AUTHOR]
- Subjects :
- *DIOXYGENASES
*FLAVONOLS
*COORDINATE covalent bond
*BENZOIC acid
*COPPER
Subjects
Details
- Language :
- English
- ISSN :
- 00201693
- Volume :
- 467
- Database :
- Academic Search Index
- Journal :
- Inorganica Chimica Acta
- Publication Type :
- Academic Journal
- Accession number :
- 125056286
- Full Text :
- https://doi.org/10.1016/j.ica.2017.07.037