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Copper-Catalyzed Borylacylation of Activated Alkenes with Acid Chlorides.
- Source :
-
Angewandte Chemie . 10/16/2017, Vol. 129 Issue 43, p13499-13503. 5p. - Publication Year :
- 2017
-
Abstract
- A method for the copper-catalyzed borylacylation of activated alkenes is presented. The reaction involves borylcupration of the alkene, followed by capture of the generated alkyl-copper intermediate with an acid chloride. The reactions operated with low catalyst loading and generally occurre within 15 min at room temperature for a range of activated alkenes. In the case of vinyl arenes, enantioselective borylacylation was possible. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00448249
- Volume :
- 129
- Issue :
- 43
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 125592230
- Full Text :
- https://doi.org/10.1002/ange.201707323