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Orientation related electrocaloric effect and dielectric phase transitions of relaxor PMN-PT single crystals.
- Source :
-
Ceramics International . Dec2017, Vol. 43 Issue 18, p16300-16305. 6p. - Publication Year :
- 2017
-
Abstract
- Orientation related phase transitions of 0.76Pb(Mg 1/3 Nb 2/3 )O 3 -0.24PbTiO 3 single crystals are studied. Values of the relaxation parameters ( γ = 1.87–1.97) estimated from linear fits of the modified Curie-Weiss law indicate the relaxor nature. For (110) oriented single crystal, typical oxygen vacancies related high temperature dielectric relaxation behaviors are observed and analyzed. Orientations dependent electrocaloric effects of 0.76Pb(Mg 1/3 Nb 2/3 )O 3 -0.24PbTiO 3 single crystals are first studied and reported, large reversible adiabatic temperature change (0.80 K) and isothermal entropy change (0.66 J K −1 kg −1 ) are observed. Giant refrigeration efficiency (43.52) and high electrocaloric coefficient (0.041 K cm kV −1 ) exceed the electrocaloric effect values in most bulk ferroelectrics in previous reports. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 02728842
- Volume :
- 43
- Issue :
- 18
- Database :
- Academic Search Index
- Journal :
- Ceramics International
- Publication Type :
- Academic Journal
- Accession number :
- 125706401
- Full Text :
- https://doi.org/10.1016/j.ceramint.2017.08.217