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Difluorocarbene for Dehydroxytrifluoromethylthiolation of Alcohols.
- Source :
-
Journal of Organic Chemistry . 10/20/2017, Vol. 82 Issue 20, p11206-11211. 6p. - Publication Year :
- 2017
-
Abstract
- Dehydroxytrifluoromethylthiolation of alcohols with a Ph3P+CF2CO2-/S8/F- system is described. Difluorocarbene generated from Ph3P+CF2CO2- would readily combine with elemental sulfur to furnish S-CF2. S-CF2 can be considered as a bifunctional intermediate, activating alcohol and providing scaffold for CF3S- formation, thus allowing for the convenient dehydroxytrifluoromethylthiolation of alcohols. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00223263
- Volume :
- 82
- Issue :
- 20
- Database :
- Academic Search Index
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 125846100
- Full Text :
- https://doi.org/10.1021/acs.joc.7b01701