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Thermal and light induced spin crossover in a mononuclear iron(II) complex.
- Source :
-
Inorganic Chemistry Communications . Nov2017, Vol. 85, p37-40. 4p. - Publication Year :
- 2017
-
Abstract
- A mononuclear complex {Fe(L) 2 [N(CN) 2 ] 2 } ( 1 ) has been synthesized through the reaction of (naphth-1-yl)-N-(3,5-di(pyridin-2-yl)-4H-1,2,4-triazol-4-yl)methanimine (L) with Fe[N(CN) 2 ] 2 . Magnetic measurement reveals that 1 exhibits a thermal induced one-step spin crossover behavior with transition temperature T 1/2 of 75 K. Furthermore, the light induced excited spin state trapping effect is observed on 1 . [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13877003
- Volume :
- 85
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry Communications
- Publication Type :
- Academic Journal
- Accession number :
- 126042338
- Full Text :
- https://doi.org/10.1016/j.inoche.2017.05.020