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Large Parity Violation Effects in the Vibrational Spectrum of Organometallic Compounds.

Authors :
Schwerdtfeger, Peter
Bast, Radovan
Source :
Journal of the American Chemical Society. 2/18/2004, Vol. 126 Issue 6, p1652-1653. 2p.
Publication Year :
2004

Abstract

The understanding of chirality is central to molecular sciences. Scientists define chirality as exhibited by systems that exist in two distinct enantiomeric states that are interconverted by the parity operation or space inversion, but not by time reversal combined with any proper spatial rotation. Conservation of parity symmetry manifests itself in enantiomers having exactly the same chemical and physical properties in an achiral medium. According to the standard model, the neutral weak electron-nucleon current leads to parity violation and breakdown of mirror image symmetry or parity nonconservation (PNC) in chiral molecules, thus causing a small energy difference PNC between enantiomers resulting in small differences in spectroscopic properties.

Details

Language :
Spanish
ISSN :
00027863
Volume :
126
Issue :
6
Database :
Academic Search Index
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
12622866
Full Text :
https://doi.org/10.1021/ja038383z