Construction of new cross-linked supramolecular polymer with FRET phenomenon based on oligo(p-phenylenevinylene)-linked pillar[5]arene dimer.

Cross-linked supramolecular polymers generally show distinct mechanical properties with intriguing functions, which have become one of the hot research topics in recent years. However, the cross-linked supramolecular polymers functionalised with fluorescence resonance energy transfer (FRET) properties have been rarely reported yet. Herein, a new cross-linked supramolecular polymer equipped with efficient FRET property was constructed successfully. The oligo(p-phenylenevinylene)-linked pillar[5]arene dimer (PA-OPV) functioned as a host and energy donor, while four pentanenitrile groups coupled porphyrin (CN-Por) acted as guest with energy acceptor. The supramolecular polymerisation and FRET properties were investigated by using NMR, viscosity, Fluorescence, UV–vis and SEM. A new cross-linked supramolecular polymer equipped with efficient FRET property was constructed successfully, the oligo(p-phenylenevinylene)-linked pillar[5]arene dimer (PA-OPV) functioned as both host and energy donor, while four pentanenitrile groups coupled porphyrin (CN-Por) acted as guest with energy acceptor. The supramolecular polymerization and FRET properties were investigated by using NMR, viscosity, Fluorescence, UV–vis and SEM. [ABSTRACT FROM PUBLISHER]