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Slow magnetic relaxation in luminescent mononuclear dysprosium(iii) and erbium(iii) pentanitrate complexes with the same LnO10 coordination geometry.
- Source :
-
Dalton Transactions: An International Journal of Inorganic Chemistry . 12/7/2017, Vol. 46 Issue 45, p15812-15818. 7p. - Publication Year :
- 2017
-
Abstract
- Two isostructural mononuclear Dy and Er pentanitrate complexes with an LnO10 coordination geometry have been synthesized and studied by single-crystal X-ray diffraction, luminescence and magnetic measurements. Slow relaxation of the magnetization behavior is simultaneously observed in two complexes with the same coordination environment, despite the different types of the 4f-shell electron distribution. Meanwhile, both complexes exhibit the respective characteristic Ln(iii) photoluminescence. [ABSTRACT FROM AUTHOR]
- Subjects :
- *DYSPROSIUM compounds
*ERBIUM compounds
*MAGNETIC relaxation
Subjects
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 46
- Issue :
- 45
- Database :
- Academic Search Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 126346893
- Full Text :
- https://doi.org/10.1039/c7dt02905e