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Regioselective Synthesis of Selenide Ethers through a Decarboxylative Coupling Reaction.
- Source :
-
Advanced Synthesis & Catalysis . 11/23/2017, Vol. 359 Issue 22, p3950-3961. 12p. - Publication Year :
- 2017
-
Abstract
- An efficient and selective approach to the synthesis of selenide ethers containing one or two geminal C-Se bonds from readily available diselenides and phenylacetic acids was developed. Compounds containing one C-Se bond were prepared by employing air as the oxidant under metal-free conditions, whereas compounds having two geminal C-Se bonds were formed via the iron(III) chloride/oxygen/cesium carbonate (FeCl3/O2/Cs2CO3) system. Moreover, 1,2-diphenyldisulfane also could be smoothly converted into the corresponding sulfur ether product under the standard reaction conditions. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 16154150
- Volume :
- 359
- Issue :
- 22
- Database :
- Academic Search Index
- Journal :
- Advanced Synthesis & Catalysis
- Publication Type :
- Academic Journal
- Accession number :
- 126406705
- Full Text :
- https://doi.org/10.1002/adsc.201700676