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Relaxation and conduction mechanism of BNT-KNN ceramics by impedance study.
- Source :
-
Ferroelectrics . 2017, Vol. 517 Issue 1, p58-65. 8p. - Publication Year :
- 2017
-
Abstract
- Impedance spectra of 0.93BNT-0.07KNN revealed positive and negative temperature coefficient of resistance behaviour up to 400°Cand above 400°C. With the increase of temperature, decreased radii and displaced centres of semicircles from the real axis of impedance Cole-Cole plots suggested non-Debye type relaxation mechanism. Three dielectric relaxation regions: within (i) grain, (ii) grain- grain boundary and (iii) grain boundary were prominent in lower, middle and high temperature regions, respectively. The activation energy ranging from ∼0.79 to 1.2eV, suggested that the conduction carriers were cation and cation, oxygen vacancies in lower and higher temperature regions, respectively. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00150193
- Volume :
- 517
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Ferroelectrics
- Publication Type :
- Academic Journal
- Accession number :
- 126433696
- Full Text :
- https://doi.org/10.1080/00150193.2017.1369835