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N-substituted-3(10H)-acridones as visible-light photosensitizers for organic photoredox catalysis.
- Source :
-
Tetrahedron . Jan2018, Vol. 74 Issue 4, p483-489. 7p. - Publication Year :
- 2018
-
Abstract
- N-Substituted-3(10H)-acridones have been established as visible-light organic photocatalyst. These photosensitizers are efficient for oxidative coupling reaction of N-aryl tetrahydroisoquinolines with various nucleophiles. Notably, N-methyl-3(10H)-acridone ( Ia ) is stable and can be effectively prepared. It is a water-soluble and atom-economic catalyst, and thus holds promise for green chemical applications. Mechanistic studies confirm a single electron transfer (SET)-induced radical process and a rate-limiting step. Analysis of the photocatalytic reactivity−structure relationship reveals that the acridones are robust and tunable photosensitizers for photoredox catalysis. [ABSTRACT FROM AUTHOR]
- Subjects :
- *VISIBLE spectra
*PHOTOSENSITIZERS
*PHOTOCATALYSIS
*NUCLEOPHILES
*CHARGE exchange
Subjects
Details
- Language :
- English
- ISSN :
- 00404020
- Volume :
- 74
- Issue :
- 4
- Database :
- Academic Search Index
- Journal :
- Tetrahedron
- Publication Type :
- Academic Journal
- Accession number :
- 127034365
- Full Text :
- https://doi.org/10.1016/j.tet.2017.12.019