Back to Search Start Over

Cobalt‐Catalyzed Coupling of Benzoic Acid C−H Bonds with Alkynes, Styrenes, and 1,3‐Dienes.

Authors :
Nguyen, Tung Thanh
Grigorjeva, Liene
Daugulis, Olafs
Source :
Angewandte Chemie. 2/5/2018, Vol. 130 Issue 6, p1704-1707. 4p.
Publication Year :
2018

Abstract

Abstract: A method for cobalt‐catalyzed, carboxylate‐directed functionalization of arene C−H bonds is reported. Alkynes, styrenes, and 1,3‐dienes can be coupled with benzoic acids to provide cyclic products in good yields. The reactions proceed in the presence of a cobalt(II) hexafluoroacetylacetonate catalyst, (TMS)2NH base, Ce(SO4)2 cooxidant, and oxygen oxidant. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00448249
Volume :
130
Issue :
6
Database :
Academic Search Index
Journal :
Angewandte Chemie
Publication Type :
Academic Journal
Accession number :
127666651
Full Text :
https://doi.org/10.1002/ange.201711968