Preparation of the Au@TiO2 nanofibers by one-step electrospinning for the composite photoanode of dye-sensitized solar cells.

The TiO 2 nanofibers containing Au nanoparticles (NPs) were synthesized via one-step electrospinning of TiO 2 precursor, HAuCl 4 ·3H 2 O, and polyvinylpyrrolidone (PVP) in DMF solution followed by pyrolysis. The amount of Au NPs in the Au@TiO 2 nanofibers was varied by the concentration of HAuCl 4 ·3H 2 O in the electrospinning solution. The formation of the Au@TiO 2 nanofibers during the pyrolysis process was characterized by SEM, TEM, TGA, and UV/Vis. Dye-sensitized solar cells (DSSCs) based on composite photoanode of the Au@TiO 2 nanofibers and the TiO 2 nanoparticles were investigated. The results indicated that the efficiency of the DSSC would be enhanced by the optimal amount of Au NPs ( i.e. , 0.5 wt.%) in the Au@TiO 2 nanofibers. [ABSTRACT FROM AUTHOR]