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Visible light-promoted tandem azidation/cyclization of N-arylenamines towards quinoxalines.
- Source :
-
Journal of Photochemistry & Photobiology A: Chemistry . Mar2018, Vol. 355, p382-388. 7p. - Publication Year :
- 2018
-
Abstract
- This paper reports that N -arylenamines can be converted into quinoxalines via tandem azidation/intramolecular C H amination under visible light irradiation by using 1-azidyl-1,2-benziodoxole as the azidating agent. The substituent was found to have a critical influence on the reaction, and thus different conditions were required to fit the substrates of varied structural features. The conversion of N -aryl-3-arylenamine esters into the corresponding quinoxalines proceeded well under metal-free conditions, whereas Cu(OAc) 2 was required when N -aryl-3-trifluoromethyl enamine esters were used as the substrates. This method was also applied to the preparation of 2,3-diarylquinoxalines by using Ru(bpy) 3 Cl 2 as the photoredox catalyst. The reactions revealed herein provide an efficient approach towards quinoxalines. [ABSTRACT FROM AUTHOR]
- Subjects :
- *QUINOXALINES
*AZIDATION
*IRRADIATION
*AMINATION
*ENAMINES
Subjects
Details
- Language :
- English
- ISSN :
- 10106030
- Volume :
- 355
- Database :
- Academic Search Index
- Journal :
- Journal of Photochemistry & Photobiology A: Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 128348573
- Full Text :
- https://doi.org/10.1016/j.jphotochem.2017.07.043