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Synthesis of dithioureado-bridged bis-pillar[5]arenes and formation of unique bis-[1]rotaxanes.
- Source :
-
Supramolecular Chemistry . Jul2018, Vol. 30 Issue 7, p642-647. 6p. - Publication Year :
- 2018
-
Abstract
- The addition reaction of mono-amide-functionalized pillar[5]arenes with 1,4-diisothiocyanatobenzene or 1,4-diisothiocyanatohexane in chloroform resulted in various dithioureado-bridged bis-pillar[5]arenes. 1H and 2D NMR spectroscopy as well as X-ray single crystal structure indicated that the longer dithioureado chain threaded into both cavities of the two pillar[5]arenes to form the unique bis-[1]rotaxane structures in solution and in solid state. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10610278
- Volume :
- 30
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- Supramolecular Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 128864233
- Full Text :
- https://doi.org/10.1080/10610278.2018.1427238