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Preparation of Iron(II) Water-Soluble Compounds Based on Iron(0), (1-Hydroxyethylidene)diphosphonic Acid, and Organic Amines.
- Source :
-
Russian Journal of General Chemistry . Mar2018, Vol. 88 Issue 3, p509-513. 5p. - Publication Year :
- 2018
-
Abstract
- The reaction of aqueous suspension of finely dispersed iron with one equivalent of (1-hydroxyethylidene) diphosphonic acid (H4L) results in poorly soluble iron(II) (1-hydroxyethylidene)diphosphate FeH2L·H2O. The reaction with two equivalents of the acid gives a water-soluble compound Fe(H3L)2, which undergoes disproportionation up to FeH2L·H2O and H4L. The reaction of a FeH2L·H2O aqueous suspension with an organic amine results in the dissolution of the complex. Heating the FeH2L·H2O aqueous suspension in a pressure reactor at 150°C in the presence of KF catalytic amounts causes the formation of a new crystal phase and X-ray-amorphous admixtures. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10703632
- Volume :
- 88
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- Russian Journal of General Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 129132694
- Full Text :
- https://doi.org/10.1134/S1070363218030180