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Synthesis of 1-amino-12-hydroxyl-perylene tetra-(alkoxycarbonyl) for selective sensing of fluoride.
- Source :
-
Dyes & Pigments . Sep2018, Vol. 156, p225-232. 8p. - Publication Year :
- 2018
-
Abstract
- A perylene tetra-(alkoxycarbonyl) derivative (compound 2 ) substituted with amino and hydroxyl at the same side was synthesized through an intramolecular rearrangement mechanism. Its chemical structure was fully confirmed by NMR, FT-IR, HRMS spectra and was further confirmed by a cyclic condensation reaction to yield a seven membered heterocycle annulated compound 3 . The properties of them were detected by absorption, fluorescence spectra and electrochemical response. Compound 2 was used as colorimetric and fluorescent probe for fluoride ion detection with remarkable selectivity owing to the intermolecular proton transfer (IPT) process between hydroxyl group and the fluoride ion. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 01437208
- Volume :
- 156
- Database :
- Academic Search Index
- Journal :
- Dyes & Pigments
- Publication Type :
- Academic Journal
- Accession number :
- 129682758
- Full Text :
- https://doi.org/10.1016/j.dyepig.2018.04.012