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Palladium-catalyzed desulfitative arylation of sulfonamides with sodium arylsulfinates.
- Source :
-
Synthetic Communications . 2018, Vol. 48 Issue 12, p1436-1442. 7p. 3 Diagrams, 3 Charts. - Publication Year :
- 2018
-
Abstract
- A Pd(II)-catalyzed desulfitative arylation protocol between sulfonamides and sodium arylsulfinates was herein reported. The direct arylation reaction was successfully achieved by a Pd(II)/Ag(I)-mediated system without participation of any external ligands with a release of SO2. And different N-aryl sulfonamides were obtained readily in up to 86% yields, exhibiting good functional groups tolerance (25 examples). [ABSTRACT FROM AUTHOR]
- Subjects :
- *PALLADIUM catalysts
*ARYLATION
*SULFONAMIDES
*CHEMICAL reactions
*FUNCTIONAL groups
Subjects
Details
- Language :
- English
- ISSN :
- 00397911
- Volume :
- 48
- Issue :
- 12
- Database :
- Academic Search Index
- Journal :
- Synthetic Communications
- Publication Type :
- Academic Journal
- Accession number :
- 129754734
- Full Text :
- https://doi.org/10.1080/00397911.2018.1452262