Effect of toluene adsorption on permeation through SAPO-34 membranes.

When 0.65 mol% toluene was added to SAPO-34 membrane feeds (172-kPa feed pressure), the CO 2 and N 2 permeances decreased by approximately 50%, even though toluene is too large to diffuse into the SAPO-34 pores. Single-component adsorption isotherms for CO 2 and toluene were used to fit a dual-site Langmuir model to estimate external surface coverages. The lower CO 2 permeances qualitatively correlated with the reduced CO 2 surface coverages. Changes in permeances for 10-kPa feed pressures were also measured so that surface coverages could be estimated more accurately using ideal adsorbed solution theory. The estimated decreases in CO 2 coverages on the membrane surface due to competitively-adsorbed toluene reduced the trans-membrane CO 2 driving force and accounted for the observed decreases in permeance. [ABSTRACT FROM AUTHOR]