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Stereoselective synthesis of cyclopentafullerenes: the reaction of [60]fullerene with aldehydes and triethylamine promoted by magnesium perchlorate.
- Source :
-
New Journal of Chemistry . 6/7/2018, Vol. 42 Issue 11, p9291-9299. 9p. - Publication Year :
- 2018
-
Abstract
- The magnesium perchlorate-mediated reaction of [60]fullerene with aldehydes and triethylamine under air conditions afforded a series of rare cyclopentafullerenes in moderate to good yields with high stereoselectivity. A plausible reaction mechanism was suggested to elucidate the formation of cyclopentafullerenes. [ABSTRACT FROM AUTHOR]
- Subjects :
- *FULLERENES
*TRIETHYLAMINE
*STEREOSELECTIVE reactions
Subjects
Details
- Language :
- English
- ISSN :
- 11440546
- Volume :
- 42
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- New Journal of Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 129864303
- Full Text :
- https://doi.org/10.1039/c8nj01578c