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Manganese-Catalyzed Direct Conversion of Ester to Amide with Liberation of H2.
- Source :
-
Organic Letters . 6/1/2018, Vol. 20 Issue 11, p3381-3384. 4p. - Publication Year :
- 2018
-
Abstract
- A simple and efficient Mn-catalyzed acylation of amines is achieved using both acyl and alkoxy functions of unactivated esters with the liberation of molecular hydrogen as a sole byproduct. The present protocol provides an atom-economical and sustainable route for the synthesis of amides from esters by employing an earth-abundant manganese salt and inexpensive phosphine-free tridentate ligand. [ABSTRACT FROM AUTHOR]
- Subjects :
- *AMIDES
*ESTERS analysis
*ALKOXY compounds
*OXYGEN compounds
*MANGANESE alloys
Subjects
Details
- Language :
- English
- ISSN :
- 15237060
- Volume :
- 20
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- Organic Letters
- Publication Type :
- Academic Journal
- Accession number :
- 130011157
- Full Text :
- https://doi.org/10.1021/acs.orglett.8b01305