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In situ atomic-scale observation of inhomogeneous oxide reduction.

Authors :
Chen, Xiaobo
Wu, Dongxiang
Zou, Lianfeng
Yin, Qiyue
Zhang, Hanlei
Zakharov, Dmitri N.
Stach, Eric A.
Zhou, Guangwen
Source :
Chemical Communications. 7/7/2018, Vol. 54 Issue 53, p7342-7345. 4p.
Publication Year :
2018

Abstract

We report in situ atomic-scale transmission electron microscopy observations of the surface dynamics during Cu2O reduction. We show inhomogeneous oxide reduction caused by the preferential adsorption of hydrogen at step edges that induces oxygen loss and destabilizes Cu atoms within the step edge, thereby resulting in the retraction motion of atomic steps at the oxide surface. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
54
Issue :
53
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
130392146
Full Text :
https://doi.org/10.1039/c8cc03822h