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Temperature-controlled spontaneous resolution of enantiomerically threefold interpenetrating arm-shaped MOFs with achiral symmetrical ligands.
- Source :
-
Inorganic Chemistry Communications . Aug2018, Vol. 94, p104-107. 4p. - Publication Year :
- 2018
-
Abstract
- Hydrothermal reaction of flexible 4,4′-oxybis(benzoic acid) (H 2 oba), semi-rigid 2,5-bis(4-pyridyl)-1,3,4-thiadiazole (bpt) and Cu(OH) 2 led to an interesting 2D → 3D polythreaded architecture of MOF [Cu 2 (bpt) 2 (oba) 2 (H 2 O)] n ·4nH 2 O ( 1 ). Accomplished with the rising synthesis temperature, two chiral MOFs [Cu 4 (bpt) 4 (oba) 4 ] n ( L - 2 and D - 2 ), have been obtained from the congenetic nonchiral precursors upon spontaneous resolution, which represent a rarely example of temperature-induced threefold interpenetrating enantiomerically arm-shaped MOFs constructed from achiral symmetrical ligands. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13877003
- Volume :
- 94
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry Communications
- Publication Type :
- Academic Journal
- Accession number :
- 130542565
- Full Text :
- https://doi.org/10.1016/j.inoche.2018.06.007