A convenient synthesis of (E)-conjugated polyene sulfonyl derivatives with excellent stereospecificity.

Authors :: Yu, Chunyan
Lv, Zhongwen
Xu, Sheng
Zhang, Jun
Source :: Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry. Aug2018, Vol. 59 Issue 34, p3234-3237. 4p.
Publication Year :: 2018
Abstract: A highly selective synthesis of conjugated polyene sulfonyl derivatives is described via the elimination of disulfonyl chloride with readily accessible raw material dihaloalkane. The protocol offers a convenient way to form sulfonamides, sulfonates and even sulfones. Furthermore, this method was manipulated under mild condition with simple operation in high yield to afford only trans products. [ABSTRACT FROM AUTHOR]

Subjects :: *SULFONAMIDES
*STEREOSPECIFICITY
*RAW materials
*SULFONATES
*SULFONES

Language :: English
ISSN :: 00404039
Volume :: 59
Issue :: 34
Database :: Academic Search Index
Journal :: Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
Publication Type :: Academic Journal
Accession number :: 130949298
Full Text :: https://doi.org/10.1016/j.tetlet.2018.05.060

Full Text Access

Tools