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Rapid microwave-hydrothermal preparation of few-layer MoS2/C nanocomposite as anode for highly reversible lithium storage properties.
- Source :
-
Journal of Materials Science . Oct2018, Vol. 53 Issue 20, p14548-14558. 11p. 1 Color Photograph, 1 Diagram, 5 Graphs. - Publication Year :
- 2018
-
Abstract
- 3D nanohybrid structures with few-layered MoS2 nanosheets uniformly incorporated in the carbon substrate are prepared via using the rapid and homogeneous microwave-hydrothermal method, in which the size of the basic unit structure of MoS2/C was small. The samples were systematically investigated by X-ray diffraction, field emission scanning electron microscopy, X-Ray photoelectron spectroscopy and high-resolution transmission electron microscopy for structure and composition test. The electrochemical performances of the composites are evaluated by cyclic voltammogram, galvanostatic charge-discharge and electrochemical impedance spectroscopy. Electrochemical measurements reveal that the maximum-specific capacitance of the MoS2/C electrodes reaches up to 1003 mAh g-1 at a discharge current density 100 mA g-1. The MoS2/C hybrid composite remains 755 mAh g-1 after 50 cycles at the current of 200 mA g-1, much higher than that of the pure MoS2. The superior electrochemical performances of MoS2/C composites as Li-ion battery anodes are attributed to their enhanced available active sites for charges, decreased transmission resistance between interlayers, improved electronic conductivity as well as good mechanical stability. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00222461
- Volume :
- 53
- Issue :
- 20
- Database :
- Academic Search Index
- Journal :
- Journal of Materials Science
- Publication Type :
- Academic Journal
- Accession number :
- 131034679
- Full Text :
- https://doi.org/10.1007/s10853-018-2631-7