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Three-dimensional MoO2@few-layered MoS2 covered by S-doped graphene aerogel for enhanced lithium ion storage.
- Source :
-
Electrochimica Acta . Sep2018, Vol. 283, p619-627. 9p. - Publication Year :
- 2018
-
Abstract
- MoO 2 with low electrical resistivity and high specific capacity as anode for lithium ion batteries is hindered because of its large volume variation during Li + insertion/extraction process, which leads to fast capacity fading. Herein, three-dimensional (3D) core-shell MoO 2 @few-layered MoS 2 covered by S-doped graphene (MO/MS/SG) aerogel has been fabricated through hydrothermal reaction and freeze-drying process together with sulfidation. MoO 2 nanoparticles coated by few-layer MoS 2 can promote good dispersion of MoO 2 nanoparticles and avoid the restacking of MoS 2 . S doping in graphene can increase the defects and active sites. S-doped graphene aerogel as flexible framework and conductive network not only provides the transmission path for ions and electrons, but also maintains the structural integrity of electrode during cycles. Core-shell MoO 2 @few-layer MoS 2 hybrid well-dispersed in S-doped graphene matrix buffers the volume changes during cycles and contributes to high reversible capacity. Free-standing electrode without binder and current collector prevents the separation of electrode materials from current collector during cycles. Benefitting from the unique structures, the MO/MS/SG aerogel as anode for lithium ion battery exhibits high reversible capacities of 683 mAh g −1 at 0.1 A g −1 after 100 cycles and 533 mAh g −1 at 0.5 A g −1 after 350 cycles together with excellent rate capability. This work demonstrates the potential application of the Mo-based materials in lithium ion batteries. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00134686
- Volume :
- 283
- Database :
- Academic Search Index
- Journal :
- Electrochimica Acta
- Publication Type :
- Academic Journal
- Accession number :
- 131130724
- Full Text :
- https://doi.org/10.1016/j.electacta.2018.07.011