A systematic review on CO2 capture with ionic liquids: Current status and future prospects.

Abstract Global warming due to the emission of greenhouse gases, especially carbon dioxide (CO 2), has a significant effect on the climate change and has become a widespread concern in the recent years. Carbon capture, utilization, and sequestration (CCUS) strategy appears to be effective in decreasing the carbon dioxide level in the atmosphere. Despite a great progress in this field, there are still major limitations in commercialized the CO 2 capture methods that rely on absorption phenomena. High capital costs of for the CO 2 capture, low absorption and desorption rates (which require large facilities), solvent losses due to evaporation, and the use of corrosive solvents are among main obstructions. Recently, CO 2 capture with ionic liquids (ILs) has appreciably attracted researchers’ attention. The distinct properties of ILs such as negligible vapor pressure and their affinity to capture the CO 2 molecules make them a feasible alternative for currently available solvents including, different amines. This paper covers a brief review of previous engineering and research works on various CO 2 capture techniques, the description of CO 2 capture process using ILs, mechanisms of the CO 2 capture with ILs at molecular level, CO 2 and ILs properties, characterization of the CO 2 /IL systems, impacts of operating and fluids conditions on CO 2 absorption capacity by ILs, and CO 2 solubility and selectivity in ILs. Moreover, the technical and economic aspects of the CO 2 capture with ILs, screening criteria for ILs/CO 2 systems, and important results obtained from previous studies will form the last parts of this manuscript. This review offers a proper/systematic guideline that assists researchers and engineers to comprehensively understand and to effectively design the CO 2 /ILs processes, focusing on the thermodynamic and mass transfer aspects. Highlights • CO 2 capture with ionic liquids (ILs) appears to be a promising strategy in the future. • This review paper describes carbon capture process using ILs, mechanisms, and challenges. • This paper discusses about different characterization tools for ILs/CO 2 systems. • CO 2 capture efficiency is studied at various conditions through parametric sensitivity analysis. • Technical and economic aspects and screening criteria for ILs/CO 2 systems are highlighted. [ABSTRACT FROM AUTHOR]