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Cover Picture: Electrochemical Synthesis of (Aza)indolines via Dehydrogenative [3+2] Annulation: Application to Total Synthesis of (±)‐Hinckdentine A (Chin. J. Chem. 10/2018).

Authors :
Hou, Zhong‐Wei
Yan, Hong
Song, Jin‐Shuai
Xu, Hai‐Chao
Source :
Chinese Journal of Chemistry. Oct2018, Vol. 36 Issue 10, p889-889. 1p.
Publication Year :
2018

Abstract

The cover picture shows an electricity powered dehydrogenative [3+2] annulation reaction of (hetero)arylamines with tethered di‐, tri, and tetra‐substituted alkenes for the preparation of indoline and azaindoline products. The electrochemical reactions proceed through H2 evolution and thus avoid the use of stoichiometric chemical oxidants. This method, which is applicable to the preparation of highly functionalized (aza)indoline scaffold, enables the total synthesis of (±)‐hinckdentine A in 12 steps. More details are discussed in the article by Xu et al. on page 909–915. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
1001604X
Volume :
36
Issue :
10
Database :
Academic Search Index
Journal :
Chinese Journal of Chemistry
Publication Type :
Academic Journal
Accession number :
131777501
Full Text :
https://doi.org/10.1002/cjoc.201880101